About
the Text
The Structure of the IPS 8th Edition Course
IPS has always had a central theme and a clear story line not confined
to a single discipline. The central them is the study of matter leading
to the development of the atomic model. In broad terms, the course
divides naturally into two parts.
Chapters 1-6 provide the empirical framework without which the atomic
model becomes an answer in search of a question. The progression is
from what is around us in the greatest abundance, namely mixtures,
to compounds and elements. In the process, students learn about the
characteristic properties by which substances are recognized and separated.
Chapters 7-10 use the discreteness of radioactive processes to motivate
the development of the atomic model. The atomic model is shown to
bring order to known facts and to allow us to make testable predictions.
Simple methods are used to determine the size and masses of molecules
and atoms. The periodic table is examined through a historical perspective
and serves as a culmination of the course.
The division of the course along these lines provides natural breaking
points for teachers who wish to spread the IPS course over more than
one year or to integrate IPS with Force, Motion, and Energy.
The Story Line of the Eighth Edition of IPS
The
following annotated table of contents best describes the Eighth
Edition story line:
CHAPTER 1- VOLUME AND MASS
1.1 Experiment: Heating Baking Soda
1.2 Volume
1.3 Reading Scales
1.4 Experiment: Measuring Volume by Displacement of Water
1.5 Mass: The Equal-Arm Balance
1.6 Unequal-Arm Balances
1.7 Electronic Balances
1.8 Experiment: The Sensitivity of a Balance
As you introduce a new class to IPS, try to set the tone for the
entire year on the first day. The short note "To the Student"
(on page x in the text) and Experiment 1.1, Heating Baking Soda,
will help you do this.
The purpose of the note is to alert students to the interplay of
the three forms of active learning in the course: experimenting,
reading, and solving problems. You may wish to read the note in
class either before or after Experiment 1.1.
Raising the question of how to compare amounts of solids, liquids,
and gases at the end of Experiment 1.1 serves as a motivation for
the study of volume and mass. We begin with volume, showing different
methods of measuring it and the need to say precisely what we mean
by the volume of an object. After pointing out the shortcomings
of volume as a measure of the quantity of matter, we then proceed
to mass, which is operationally defined as that property of matter
that is measured with an equal-arm balance. However, in practice,
the course no longer requires the use of the equal-arm balance.
Experiment 1.8, in which students determine the sensitivity of a
balance, has been written so that it can be done with equal-arm
balances, unequal-arm balances, or electronic balances.
CHAPTER 2 - MASS CHANGES IN CLOSED SYSTEMS
2.1 Experiment: The Mass of Dissolved Salt
2.2 Histograms
2.3 Using a Computer to Draw Histograms
2.4 Experiment: The Mass of Ice and Water
2.5 Experiment: The Mass of Copper and Sulfur
2.6 Experiment: The Mass of a Gas
2.7 The Conservation of Mass
2.8 Laws of Nature
Although this chapter is among the shorter ones in the text, it
is of prime importance. Interwoven in it are two objectives: the
development of the skills related to the balance and the analysis
of data, and the accumulation of evidence leading to a fundamental
law of nature, the law of conservation of mass. It will take the
entire chapter to reach the objectives.
Histograms, which are introduced in this chapter, are used throughout
the course. The time you invest in teaching students how to construct
them will pay handsome dividends later on. Once students know how
to construct histograms by hand, we recommend that they use the
KaleidaGraph software to save time and explore various choices available
to them.
Emphasize to students that a single experiment, involving only one
kind of change (such as dissolving salt), is not in itself very
convincing evidence for concluding that mass does not change when
other changes take place. This is why four separate mass-conservation
experiments, all involving different kinds of change, are included
in this chapter. Do not skip any of them; let your students do all
of them to convince themselves of the plausibility of conservation
of mass.
CHAPTER 3 - CHARACTERISTIC PROPERTIES
3.1
Properties of Substances and Properties of Objects
3.2 Experiment: Mass and Volume
3.3 Density
3.4 Dividing and Multiplying Measured Numbers
3.5 Experiment: The Density of Solids
3.6 Experiment: The Density of Liquids
3.7 Experiment: The Density of a Gas
3.8 The Range of Densities
3.9 Experiment: Freezing and Melting
3.10 Graphing
3.11 Experiment: Boiling Point
3.12 Boiling Point and Air Pressure
3.13 Identifying Substances
In daily language one hears statements like "lead is heavier
than iron." Of course, lead is neither heavier nor lighter
than iron, just as lead is neither bigger nor smaller than iron.
Mass, volume, and shape are properties of objects. Properties that
do not depend on the amount of a substance are called characteristic
properties.
The characteristic properties discussed in this chapter and in Chapter
4 have been selected for their usefulness in identifying substances
and separating mixtures. Hence, we concentrate on density, freezing
point, and boiling point in this chapter, and on solubility in Chapter
4.
CHAPTER 4 - SOLUBILITY
4.1 Experiment: Dissolving a Solid in Water
4.2 Concentration
4.3 Experiment: Comparing the Concentrations of Saturated Solutions
4.4 Experiment: The Effect of Temperature on Solubility
4.5 Wood Alcohol and Grain Alcohol
4.6 Experiment: Isopropanol as a Solvent
4.7 Experiment: The Solubility of Carbon Dioxide
4.8 The Solubility of Gases
4.9 Acid Rain
4.10 Drinking Water
Solubility is a characteristic property of both the solute and the
solvent. It is expressed in a complex unit-grams of solute per 100
cm 3 of solvent. If we know the solubility of a substance in a given
solvent and the quantity we want to dissolve, we can calculate the
minimum amount of solvent necessary. Or, if we know how much solvent
we have, we can use the solubility to find the maximum amount of
the solute that will dissolve in it.
Like density, solubility changes with temperature. However, the
solubility of some substances changes rather dramatically with temperature,
whereas the density of solids or liquids changes only slightly.
The dependence of solubility on temperature is very useful in separating
substances in solution.
CHAPTER 5 - THE SEPARATION OF MIXTURES
5.1 Experiment: Fractional Distillation
5.2 Petroleum
5.3 The Separation of Insoluble Solids
5.4 Experiment: The Separation of a Mixture of Solids
5.5 The Separation of a Mixture of Soluble Solids
5.6 Experiment: Paper Chromatography
5.7 A Mixture of Gases: Nitrogen and Oxygen
5.8 Mixtures and Pure Substances
As we mentioned earlier, one of the criteria for selecting characteristic
properties for discussion is their usefulness in separating substances.
Now we will employ these properties for actual separations in the
laboratory, describe some applications of these methods in industry,
and arrive at an operational definition of a pure substance.
Reading through this chapter, you may get the impression that we
are leaving students with a rather vague definition of a pure substance.
This is true. The boundary between a mixture and a pure substance
is not so sharp as may be believed from reading some textbooks.
If your students realize at the end of this chapter that a pure
substance is something that cannot be broken up by any of the methods
discussed, they will have learned their lesson.
CHAPTER 6 - COMPOUNDS AND ELEMENTS
6.1 Breaking Down Pure Substances
6.2 Experiment: The Decomposition of Water
6.3 The Synthesis of Water
6.4 Experiment: The Synthesis of Zinc Chloride
6.5 The Law of Constant Proportions
6.6 Experiment: A Reaction with Copper
6.7 Experiment: The Separation of a Mixture of Copper Oxide and
Copper 6.8 Complete and Incomplete Reactions
6.9 Experiment: Precipitating Copper
6.10 Elements
6.11 Elements Near the Surface of the Earth
By definition, pure substances are not broken up into different
components by those separation methods used to separate mixtures.
The aim of this chapter is to show that, in general, pure substances
can, nevertheless, be broken up by other means, such as applying
intense heat or an electric current. Conversely, such pure substances
(compounds) can also be synthesized from other pure substances,
but only by reacting in definite proportions.
After recalling the decomposition of two pure substances by heating,
we use electrolysis to break up water (Experiment 6.2). New pure
substances are produced that are quite different from the original
substance. We then reverse our method of attack and synthesize compounds.
The examples used are chosen to illustrate one of the basic differences
between compounds and mixtures: unlike mixtures, compounds can be
synthesized only by reacting the components in definite proportions
(Sections 6.3 - 6.5).
Early difficulties in the formation of the law of constant proportions
sprang in part from the difficulty of determining when a reaction
was complete. The reaction between copper and oxygen (Experiments
6.6 and 6.7) illustrates this circumstance: The investigation into
what has happened leads to an understanding of complete and incomplete
reactions.
Experiment 6.9 ends the sequence of experiments that started with
Experiment 6.6 and continued in Experiment 6.7. Copper was used
to form a series of pure substances and was then recovered, suggesting
that the copper was there all along. The section leads into the
operational definition of elements (Section 6.10). The reasoning
used in the definition of an element is reinforced with two historical
examples. Be sure to spend enough time on this section.
Section 6.11 balances the preceding discussion of scientific methodology
with a discussion of the abundance of elements near the surface
of the earth.
CHAPTER 7 - RADIOACTIVITY
7.1 Radioactive Elements
7.2 Radioactive Decomposition
7.3 Experiment: Radioactive Background
7.4 Experiment: Collecting Radioactive Material on a Filter
7.5 Experiment: Absorption and Decay
7.6 A Closer Look at Radioactivity
7.7 Radioactivity and Health
You may wonder why we proceed with the introduction of radioactivity
at this point in the course. Here are the reasons:
(i) It provides an excellent example of the surprises that nature
has in store for us: Now that students have learned how elements
survive in the formation of compounds, they find that some elements
actually change into other elements all on their own.
(ii) This change takes place in discrete steps, which can be counted.
(iii) Taken together, (i) and (ii) provide a motivation for the
atomic model of matter and lead to a testable prediction (Chapter
8).
(iv) Being able to count radioactive decays enables us to find the
number of atoms in a given sample of an element. This, in turn,
provides a conceptually simple way to find the mass of single atoms
solely with the knowledge students gained in this course (Chapter
9).
(v) Knowing the mass of atoms enables us to introduce the periodic
table in a meaningful way (Chapter10).
In addition, it should be noted that radioactivity is largely ignored
in the science curriculum. For many students, learning about radioactivity
in IPS may be the only chance to do so.
Randomness, discreteness, and absorption can be demonstrated quite
easily in the classroom. However, demonstrating decay and the existence
of a half-life requires a source with a short half-life. The only
practical way to get such a source is to collect it yourself. You
will be able to do this if there is a sufficient concentration of
radon in the ground around your school, and if your school has a
closed, unventilated room in the basement in which radioactive material
can be collected from the air.
Unlike in other chapters, the three experiments in Chapter 7 are
to be done by the class as a whole rather than by pairs of students.
The reason is simple: it is unlikely that you will have enough Geiger
counters. However, if you have more than one counter, divide the
class into smaller groups and have them work in parallel. The class
will have the advantage of seeing that while the details vary, the
general trend is the same.
CHAPTER 8 - THE ATOMIC MODEL OF MATTER
8.1 A Model
8.2 Experiment: A Black Box
8.3 The Atomic Model of Matter
8.4 "Experiment": Constant Composition Using Fasteners
and Rings
8.5 Molecules
8.6 Experiment: Flame Tests of Some Elements
8.7 Experiment: Spectra of Some Elements
8.8 Spectral Analysis
8.9 "Experiment": An Analog for Radioactive Decay
8.10 Half-Life
We now introduce the atomic model of matter, which will continue
to be at the center of our attention through Chapter 10.
After a brief introduction to the meaning of a "model,"
the class applies the idea to a "black box," which provides
an opportunity to make testable predictions (Experiment 8.2).
Sections 8.3-8.5 sum up key observations made earlier in the course
in the context of the atomic model. The law of conservation of mass
and the law of constant proportions are given special attention.
In Sections 8.6 and 8.7, the class experiments with spectra of atoms
and is shown evidence that the spectra display properties of the
individual atoms rather than properties of the elements in bulk.
Finally, the atomic model is used to predict the existence of a
half-life for radioactive elements.
CHAPTER 9 - THE SIZES AND MASSES OF MOLECULES AND ATOMS
9.1 The Thickness of a Thin Layer
9.2 Experiment: The Thickness of a Thin Sheet of Metal
9.3 Experiment: The Size and Mass of an Oleic Acid Molecule
9.4 The Mass of Helium Atoms
9.5 The Mass of Polonium Atoms
9.6 Atomic Masses and Molecular Formulas
One of the key ingredients of the atomic model introduced in Chapter
8 was that atoms are very light and small, or, equivalently, that
there are many atoms in any sample of an element of measurable mass.
Building the atomic model on this premise demands an answer to the
question, "What is the mass of a single atom of an element?"
In this chapter we answer the question.
We arrive at our goal in stages, by preparing the students for the
main sections (Sections 9.4 and 9.5). We first find the thickness
of an aluminum foil. We then apply the same approach to find the
thickness of a layer of oleic acid (Sections 9.1-9.3).
Sections 9.4 and 9.5 parallel the film, "The Mass of Atoms,"
which is now available in VHS and DVD formats, and adds a lively
dimension to the presentation in the text. Finally, the knowledge
of atomic masses is applied to finding molecular formulas (Section
9.6).
CHAPTER 10 - THE CLASSIFICATION OF ELEMENTS:
THE PERIODIC TABLE
10.1 Introduction
10.2 Classifying Elements
10.3 The Extraction of Similar Elements from Similar Compounds
10.4 Alkali Metals, Alkaline Earth Metals, and Halogens
10.5 Activity: Atomic Mass and Other Properties of Atoms
10.6 The Elements in the Third Through Sixth Columns
10.7 Activity: Elements in the Fourth Row
10.8 The Fourth and Fifth Rows: An Historical Perspective
Chapter 10, which is new to the Eighth Edition, provides a climax
to the year's work by tying together many observations on the macroscopic
and atomic levels. We begin by asking if there is any relationship
between atomic mass and various properties of the elements (Section
10.1). This leads us to the question of how to classify elements
(Sections 10.2-10.4). Some of the historical comments extend similar
comments in Chapter 6.
To drive home the point that any classification is a matter of judgment,
we have the students do an activity with a set of 24 specially prepared
cards (Section 10.5). The cards resemble entries in a periodic table
of the elements. The activity has historical connotations, and raises
the question of the order of potassium and argon. The activity is
briefly extended in Section 10.7 to show the need for additional
columns in the periodic table.
The chapter ends with an analysis of the periodic table as a model,
and shows its success by highlighting Mendeleev's correct prediction
of the properties of germanium before the element was discovered.
APPENDIX: Calculating in Scientific Notation
Part 1 Scientific Notation
Part 2 Multiplying and Dividing in Scientific Notation:
Significant Digits
The appendix provides instruction and practice for students who
need to improve their skill calculating with numbers in scientific
notation.
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